Immobilization and activation of vanadium(III) and titanium(III) single‐site catalysts for ethylene polymerization using MgCl2‐based supports

Significant increases in the activity of vanadium(III) amidinate catalysts for ethylene polymerization have been obtained by immobilization on a MgCl₂‐based support prepared by reaction of AlEt₃ with a MgCl₂/ethanol adduct. Catalyst immobilization and activation on this type of support prevents the rapid decay in activity observed under homogeneous polymerization conditions with unsupported catalysts. Stable polymerization activity is also observed with analogous titanium(III) complexes. Polyethylene with narrow molecular weight distribution and spherical particle morphology is obtained without reactor fouling. Copyright © 2005 Society of Chemical Industry     

The new structure of fibre glass reinforced plastics bolt

The develop actuality and direction of FRP (fibre glass reinforced plastics) bolt in the world are analyzed. The new type structure of FRP bolt was designed. Trial data indicate that, all kinds of capability target of this FRP bolt all achieve and exceed the country stand-ard, substitute present metal bolt, wood bolt and bamboo bolt and other side bolt, it can gain magnitude technology and economy benefit. FRP bolt mechanization product line produce ef-ficiency is high, its throughput a day are 750 base, this can meet demand of hit-small mining company.     

基于地理信息系统的天津房地产管理数据库

从地理信息系统CIS的组成开始．提出该类系统的组织与管理方法，同时重点介绍了在现阶段开发该类系统时所使用的高端技术，最后对GIS系统的发展趋势作出分析与顶测。     

大规模训练数据的支持向量机学习新方法

支持向量机不能直接对大规模的训练数据进行学习。提出一种新的减小样本集规模的方法；在映射后的高维空间中寻找两种类别的交界部分，交界部分上的样本作为学习样本。并且指出，不需涉及具体映射的形式只用核函数即可找到交界部分的样本。实验表明，新方法优于直接在低维样本空间中寻找交界部分样本的方法。     

Forced Vertical Vibration of Circular Plate in Multilayered Poroelastic Medium

This paper considers the vertical vibrations of an elastic circular plate in a multilayered poroelastic half space. The plate is subjected to axisymmetric time–harmonic vertical loading and its response is governed by the classical thin-plate theory. The contact surface between the plate and the multilayered half space is assumed to be smooth and either fully permeable or impermeable. The half space under consideration consists of a number of layers with different thicknesses and material properties and is governed by Biot’s poroelastodynamic theory. The vertical displacement of the plate is represented by an admissible function containing a set of generalized coordinates. Contact stress and pore pressure jump are established in terms of generalized coordinates through the solution of flexibility equations based on the influence functions corresponding to vertical and pore pressure loading. Solutions for generalized coordinates are obtained by establishing the equation of motion of the plate through the application of Lagrange’s equations of motion. Selected numerical results are presented to portray the influence of various parameters on dynamic interaction between an elastic plate and a multilayered poroelastic half space.     

大孔径石蜡加氢精制催化剂的制备

采用氨吸附-程序升温脱附(NH3-TPD)、低温N2吸附(BET)、压汞法以及加氢精制活性评价等技术,探索SiO2-Al2O3载体在制备过程中孔结构和表面性质的变化。实验结果表明,采用特殊扩孔剂制备载体,当焙烧温度为700℃时,平均孔径可达到17.3nm,其中孔径大于20nm的孔占总孔体积的13.2%;同时载体表面上的中、强酸中心也全部丧失,均为弱酸中心。采用该载体制备的MoNiP/SiO2-Al2O3石蜡加氢精制催化剂,在MoO3用量减少了约1/4的情况下,比目前工业上使用的催化剂具有更高的脱金属能力和加氢精制活性。     

Breaking the search space symmetry in partitioning problems: An application to the graph coloring problem

Many problems consist in splitting a set of objects into different groups so that each group verifies some properties. In practice, a partitioning is often encoded by an array mapping each object to its group numbering. In fact, the group number of an object does not really matter, and one can simply rename each group to obtain a new encoding. That is what we call the symmetry of the search space in a partitioning problem. This property may be prejudicial for optimization methods such as evolutionary algorithms (EA) which require some diversity during the search.     

松软厚煤层轻放工作面切眼锚杆支护实践

针对朱仙庄矿 84 15工作面切眼特殊的地质条件 ,介绍了高强锚杆 (索 )支护技术成功应用于特厚极软煤层的经验 ,并对巷道支护成本进行了分析     

A new stereological principle for test lines in three-dimensional space

A new principle is presented to generate isotropic uniform random (IUR) test lines hitting a geometric structure in three-dimensional space (3D). The principle therefore concerns the estimation of surface area, volume, membrane thickness, etc., of arbitrary structures with piecewise smooth boundary. The principle states that a point-sampled test line on an isotropic plane through a fixed point in 3D is effectively an invariant test line in 3D. Particular attention is devoted to the stereology of particles, where an alternative to the surfactor method is obtained to estimate surface area. An interesting case arises when the particle is convex. The methods are illustrated with synthetic examples.     

CMYK图像的TIFF格式

为满足印前和艺术设计过程中的图像处理的需要,介绍一种基于CMYK(青-品红-黄-黑)颜色空间的图像在TIFF文件中的存储,以及对此类图像的通用处理方法。通过对TIFF文件内部结构的解析,了解如何才能准确地对一幅CMYK图像进行描述、存储和处理。另外,文中还给出使用libtiff函数库处理TIFF文件的样例。